ConditionInjuries & poisoning

Chemical Burns

A chemical burn is damage to the skin, eyes, mouth or internal organs caused by contact with an acid, alkali or other corrosive substance. Common culprits are drain and oven cleaners, bleach, cement, battery acid and pool chemicals. The most important first aid is to remove contaminated clothing and flush the area with large amounts of running water for at least 20 minutes. Alkali burns are often deeper than they first look, and burns to the eyes, face, hands or genitals, or any swallowed chemical, need emergency care.

Also called: Caustic burn, corrosive burn, acid burn, alkali burn

At a glance

What it is
Tissue damage from a corrosive chemical.
Common causes
Drain and oven cleaners (lye), bleach, cement and lime, battery acid, hydrofluoric acid, pool chemicals.
First aid
Remove clothing and jewelry, brush off powders, flush with running water for at least 20 minutes.
Most dangerous
Alkalis (deep penetration), hydrofluoric acid, eye burns and swallowed chemicals.
Treatment
Continued irrigation, wound care, pain relief, specialist burn or eye care.

When to get help

Call 911 or go to the ER

  • Any chemical in the eye: flush with water for at least 15 to 20 minutes, then call 911 or your local emergency number
  • A swallowed chemical, or burns in the mouth, drooling, difficulty swallowing or breathing
  • Burns larger than the palm of the hand, deep burns, or burns on the face, hands, feet, genitals or across joints
  • Hydrofluoric acid exposure (rust removers, glass etching), even if pain seems mild
  • Breathing difficulty, coughing or wheeze after inhaling fumes
  • Contact Poison Control (1-800-222-1222 in the US) for advice on any chemical exposure

See a doctor within a day or two

  • A small burn with blistering, increasing pain or signs of infection
  • Burns from wet cement that has been in contact with skin for some time

Book a routine appointment

  • Persistent redness or itching days after a minor splash

Usually safe to manage at home

  • A small, superficial area of redness from a household cleaner that settles after thorough rinsing

First aid for a chemical burn

  1. Protect yourself. Wear gloves if possible and avoid touching the chemical.
  2. Remove the source. Take off contaminated clothing, jewelry and watches. Cut clothing off rather than pulling it over the head.
  3. Brush off dry chemicals (such as lime or powdered cleaner) before adding water.
  4. Flush with cool running water for at least 20 minutes, longer for alkalis. Use a shower or hose for large areas. Let the water run off, not pool.
  5. Do not try to neutralize an acid with an alkali or vice versa; the reaction produces heat and worsens injury.
  6. Cover loosely with a clean, non-fluffy dressing or plastic wrap.
  7. Get medical help for anything beyond a minor burn. Keep the product container or label for the medical team.

For eye splashes, hold the eyelids open under gently running water and keep flushing on the way to care. See chemical burns of the eye.

For a swallowed chemical, do not make the person vomit, and do not give anything to drink unless Poison Control advises it.

How chemicals damage tissue

TypeExamplesHow they injureNotes
Alkalis (bases)Drain cleaner and oven cleaner (sodium hydroxide, lye), ammonia, cement and lime, some dishwasher detergentsLiquefy tissue and keep penetrating deeperOften more severe than they first appear
AcidsBattery acid (sulfuric), toilet cleaners (hydrochloric), rust removersCoagulate tissue, forming a crust that limits spreadPain usually immediate
Hydrofluoric acidRust and stain removers, glass etching, electronicsPenetrates deeply, binds calcium and magnesiumCan cause dangerous heart rhythm changes; needs calcium gluconate
OxidizersBleach, peroxide, pool chlorineIrritation to burnsFumes can injure lungs
OthersPhenol, white phosphorus, gasoline, vesicantsVariableSpecialist advice needed

Severity depends on the chemical's strength and concentration, the amount, the contact time and the area of the body.

Cement burns

Wet cement is highly alkaline. Kneeling in it or getting it inside boots or gloves can cause deep burns that are painless at first and appear hours later. Rinse immediately after any skin contact.

Symptoms

  • redness, irritation or burning pain
  • blisters or peeling
  • skin that turns white, gray, brown or black
  • numbness (from deep burns)
  • eye pain, redness, blurred vision, watering
  • after swallowing: mouth pain, drooling, vomiting, chest pain, difficulty swallowing
  • after inhaling fumes: cough, wheeze, breathlessness, throat tightness

Severity

Like thermal burns, chemical burns are classified by depth:

  • Superficial: red, painful, no blisters; heals in about a week
  • Partial thickness: blisters, very painful; heals in 2 to 3 weeks if superficial, longer if deep
  • Full thickness: white, leathery or charred, often painless; needs skin grafting

Chemical burns can deepen over hours, so initial appearance may underestimate severity.

Medical treatment

  • Continued irrigation in the emergency department, sometimes checking skin or eye pH to confirm neutralization
  • Removal of solid particles
  • Pain relief
  • Wound care: cleaning, removing dead tissue, dressings, antibiotic ointments; tetanus vaccine update
  • Specific antidotes: calcium gluconate gel or injections for hydrofluoric acid; specialist treatment for phenol and others
  • Monitoring of heart rhythm and blood calcium in hydrofluoric acid exposure
  • Endoscopy within 24 hours after swallowing a caustic substance, to grade injury to the esophagus and stomach
  • Burn center referral for large, deep or high-risk burns
  • Surgery and skin grafting for full-thickness burns

Complications

  • scarring and contractures that limit movement
  • infection
  • loss of vision after eye burns
  • narrowing (stricture) of the esophagus after swallowing caustics
  • lung damage from inhaled fumes, as with chlorine gas exposure
  • systemic poisoning with some chemicals

Prevention

  • store chemicals in original containers, locked away from children
  • never mix cleaning products (bleach plus ammonia or acids releases toxic gases)
  • wear gloves, goggles and protective clothing
  • read labels and safety data sheets at work
  • keep eyewash stations and running water accessible in workplaces

Frequently asked questions

What is the first aid for a chemical burn?

Remove contaminated clothing and jewelry, brush off any dry chemical, and flush the area with cool running water for at least 20 minutes. Do not try to neutralize the chemical. Cover loosely with a clean dressing and seek medical help for anything more than a minor burn.

Are acid or alkali burns worse?

Alkali burns are usually worse because alkalis dissolve tissue and keep penetrating deeper, so damage can be more extensive than it first looks. Acids tend to form a crust that limits spread. Hydrofluoric acid is an important exception and is especially dangerous.

How long does a chemical burn take to heal?

Superficial chemical burns usually heal within a week. Partial-thickness burns take 2 to 3 weeks or longer. Deep burns may need skin grafts and can take months, sometimes leaving scars. Healing depends on the chemical, contact time and treatment.

Should I put vinegar or baking soda on a chemical burn?

No. Neutralizing chemicals on the skin creates heat and can make the burn worse, and it delays proper flushing. Running water is the safest and most effective first aid for nearly all chemical burns.

When should I go to the hospital for a chemical burn?

Go to the ER for any eye exposure, swallowed or inhaled chemical, burns larger than your palm, deep or blistering burns, burns to the face, hands, feet, genitals or joints, and any hydrofluoric acid exposure. Call Poison Control for advice if unsure.

Sources

This guide was written from current patient and clinical guidance, including:

  • American Burn Association: Burn referral criteria; First aid for burns
  • MedlinePlus: Chemical burn or reaction
  • Poison Control (National Capital Poison Center): Chemical burns
  • NHS: Burns and scalds
  • American Academy of Ophthalmology: Chemical eye burns, first aid